J. Iran. Chem. Soc., Vol. 8, No. 4 December 2011, pp.1058~1062.

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New Reagent for a One-Step Synthesis of Gem-Chloronitro Compounds from Oximes

M.A. Zolfigola,*, A. Khazaeia,*, E. Kolvarib,*, N. Koukabia and M. Gilandousta

aFaculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran
bDepartment of Chemistry, Faculty of Science, Semnan University, Semnan, Iran

     The use of chlorine bleach (5% NaOCl) for the halogenation-oxidation of oximes to gem-chloronitro compounds is reported. Chlorine bleach afforded satisfactory yields when employed alone either at room temperature or under ultrasonic irradiation.

Keywords: Chlorine bleach, Gem-chloronitro compounds, Halogenation, Oxidation, Ultrasonic

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