Synthesis, Structure and Magnetic Property of [Ce(DMSO)2(H2O)Fe(CN)6]
Y.M. Xie* and J.H. Wu
College of Materials Science and Engineering, Huaqiao University, Quanzhou, Fujian 362021, P.R. China
(Received 12 August 2007, Accepted 30 September 2007)
The title complex, [Ce(DMSO)2(H2O)Fe(CN)6] (1), was obtained by solution reactions and structurally characterized by X-ray diffraction. The title complex is characteristic of a novel cyano-bridged two-dimensional stair-like layered structure. The magnetic property of the title complex is reported herein. The ÷MT value at 300 K is ca. 0.92 emu K mol-1. The temperature dependence behavior of molar magnetic susceptibility of the complex clearly indicates the presence of an antiferromagnetic interaction.
Keywords: Cerium complex, Crystal structure, Cyano-bridged, X-ray diffraction, Magnetic susceptibility